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Is it possible that your Alk test kit is off? I've never heard of pH getting that high with Alk that low. Then again, I'm fairly new to this.
As for the vinegar, 45ml per gallon of ATO water is too high for starters according to what I've read. Based on your 125 gallon tank size, you'll probably end up somewhere around 30-40ml per day, so divide that by the number of gallons of ATO water you're adding per day. You'll start off around 2-4ml per day.
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