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I think it should be doable, especially with enough SPS experience. ATO, heater, lights and flow. WCs to keep parameters in control. Fluctuations would be pretty high in such a small system. So I would probably pick a salt with standard sea water parameters and just dose ALK/CAL separately under careful testing regiment.
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Pittsburgh
Current Tank Info: 95g Oceanic SPS reef. 30g sump, Sicce Syncra Silent 4.0 return, Reef Octopus 2000SSS skimmer, fuge with chaeto, BRS Carbon reactor, MR1 GFO reactor, BRS 2part dosing, Tunze ATO, 2x Tunze 6095 powerheads on a Tunze 7095, Gyre 130, 2xRadions xr30w pro.
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